Process for preparing cellulose pulp filler for...

C - Chemistry – Metallurgy – 08 – L

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400/1346

C08L 51/02 (2006.01) C08F 251/02 (2006.01) C08L 61/06 (2006.01) C08L 61/20 (2006.01) C08L 61/24 (2006.01)

Patent

CA 1171578

ABSTRACT OF THE DISCLOSURE A process is provided for preparing a graft polymer- modified cellulose pulp filler from cellulose sulfite pulp having an R18 value greater than 80%, which comprises adding to the pulp a redox initiator; washing the pulp with water having a pH below 5 in an amount sufficient to adjust the redox initiator cation content to within the range from about 5 to about 1000 ppm of cellulose sulfite pulp; adding hydrogen peroxide in an amount to provide within the range from about 0.1% to about 4% H2O2 by weight of the sulfite pulp; and then reacting the pulp with at least one monomer having the formula: Image in which: R1 is hydrogen or methyl; and R2 is selected from the group consisting of nitrilo -CN, amide Image , and COOR3 groups, wherein R3 is selected from the group consisting of methyl, ethyl, n-butyl, isobutyl and 2-ethyl- hexyl; at a temperature at which grafting of the monomer onto the cellulose polymer molecule proceeds but below about 70°C for a time less than twelve hours under an inert atmosphere in a grafting ratio within the range from about 1 to about 40% and an average degree of polymeri- zation within the range from about 20 to about 4000; and then re- covering the graft polymer-modified cellulose sulfite pulp. The resulting cellulose pulp is adapted for use as a filler for thermosetting resins, Imparting to the resins increased impact strength and structural strength, improved resistance to heat distortion and shrinkage, and decreased water absorptivity.

377030

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