Process for preparing cumene hydroperoxide

C - Chemistry – Metallurgy – 07 – C

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Details

C07C 409/10 (2006.01) C07C 37/08 (2006.01) C07C 39/04 (2006.01) C07C 407/00 (2006.01)

Patent

CA 2168585

The present invention relates to the field of the production of phenol from cumene. It concerns a process for the preparation of cumene hydroperoxide, continuously, by oxidation of cumene in liquid phase, in the presence of oxygen. The process occording to the invention is carried out in the presence of at least one agent selected amongst hydroxide, carbonate of an alcaline and/or alcaline-earth metal; said agent is used in a quantity of 2 to 10 ppb (expressed in sodium hydroxide) with respect to the amount of cumene used. The invention also relates to the utilization of the hydroperoxide thus obtained for the preparation of phenol.

La présente invention se situe dans le domaine de la fabrication du phénol à partir de cumène. Elle a pour objet un procédé de préparation d'hydroperoxyde de cumène, en continu, par oxydation en phase liquide de cumène, en présence d'oxygène. Le procédé selon l'invention est réalisé en présence d'au moins un agent choisi parmi l'hydroxyde, le carbonate d'un métal alcalin et/ou alcalino-terreux; ledit agent étant utilisé dans une quantité comprise entre 2 et 10 ppb (exprimé en hydroxyde de sodium) par rapport à la quantité de cumène introduite. L'invention concerne de même l'utilisation de l'hydroperoxyde ainsi obtenu pour la préparation du phénol.

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