Process for preparing cyclopentadienyl group-containing...

C - Chemistry – Metallurgy – 07 – H

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C07H 17/00 (2006.01) C07F 7/08 (2006.01) C07F 7/12 (2006.01) C07F 7/30 (2006.01) C07F 17/00 (2006.01)

Patent

CA 2119540

Disclosed is a process for preparing a cyclopentadienyl group-containing silicon compound or a cyclopentadienyl group-containing germanium compound, comprising reacting (i) a lithium, sodium or potassium salt of a cyclopentadiene derivative with (ii) a silicon halide compound or a germanium halide compound in the presence of a cyanide or a thiocyanate. The cyanide or the thiocyanate is preferably a copper salt. According to the process of the invention, a cyclopentadienyl group-containing silicon compound or a cyclopentadienyl group-containing germanium compound, which is very useful for the preparation of a metallocene complex catalyst component, can be prepared in a high yield for a short period of time.

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