Process for preparing dialkyl carbonates

C - Chemistry – Metallurgy – 07 – C

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C07C 69/96 (2006.01) C07C 68/00 (2006.01)

Patent

CA 2122228

Process for preparing dialkyl carbonates A b s t r a c t Dialkyl carbonates can be prepared by reaction of carbon monoxide with alkyl nitrites in a continuous gas-phase reaction using a platinum metal catalyst on a metal phosphate support and adding hydrogen halide stepwise or continuously during the course of the reaction in almost quantitative selectivity; the corresponding dialkyl oxalates are formed in such small amounts that in most cases they cannot be detected.

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