Process for preparing difluoromethoxy derivatives of...

C - Chemistry – Metallurgy – 07 – C

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260/566

C07C 47/24 (2006.01)

Patent

CA 1140591

ABSTRACT OF THE DISCLOSURE The disclosure describes a process for preparing difluoromethoxy derivatives of aromatic aldehydes having a common formula: Image wherein: Ar represents an aromatic radical selected from the group consisting of the benzene and naphthalene rings; n is an integer which is 1 or 2. The above- mentioned process comprises the interaction between corres- ponding mono- or dihydroxy derivatives of aromatic aldehydes and difluoro-chloromethane at 60-70°C in the presence of caustic alkali taken in an amount of 6 to 10 moles per 1 mole of starting hydroxyaldehyde derivative. This process simplifies the preparation of difluoromethoxy derivatives of aromatic aldehydes and, at the same time, increases the yield of the end products.

351084

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