Process for preparing ferromagnetic chromium dioxide

C - Chemistry – Metallurgy – 09 – K

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C09K 3/00 (2006.01) C01G 37/02 (2006.01) G11B 5/706 (2006.01) H01F 1/00 (2006.01)

Patent

CA 1049250

ABSTRACT OF THE DISCLOSURE Ferromagnetic chromium dioxide is prepared by ther- mally decomposing, at a temperature of 250-500°C, and a pressure of at least 80 atmospheres a mixture of hydrated trivalent chromium chromate of the formula Cr2(CrO4)3. nH2O, wherein n is 8-12, and antimony or a compound thereof, the amount of antimony in the mixture being between 0.3 and 0.7% by weight based on the weight of anhydrous Cr2(CrO4)3. In another embodiment, other known modifiers for chromium dioxide, such as lanthanum, lithium, strontium, iron or lead, or a compound thereof may be added to the mixture of chromium chromate and antimony. The amount of said other modifiers is between 0.1 and 2% by weight of the ele- ment, based on the weight of anhydrous Cr2(CrO4)3.

226540

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