Process for preparing ink compositions for ink-jet printer

C - Chemistry – Metallurgy – 09 – D

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C09D 11/00 (2006.01) C09B 67/54 (2006.01)

Patent

CA 1288239

Abstract of the Disclosure: A process for preparing an aqueous-based ink com- position for use in ink-Jet printers is disclosed. The process comprises (a) forming a solution of a dye having at least one negatively charged functional group per molecule; (b) acidifying the solution; (c) cycling the solution through a reverse osmosis membrane to form a concentrate and a permeate, the concentrate including a cation of the compound associated with at least one functional group on the dye and the permeate including a cation formerly associated with at least one funtional group; (a) adding water as necessary; (e) concentrating the dye by reverse osmosis; and (f) admixing the concentrated aye with at least one glycol etner. The ph of the ink composition is maintained below about 7. The formulation of` the final ink composition com- prises: (a) a vehicle of about 5 to 95% water and the balance at least one glycol ether, such as diethylene glycol; (b) a dye, such as Food Black 2, having at least one negatively charged functional group per molecule, present in an amount up to about 10% of the vehicle composition; and (c) a cationic compound selected from the group consisting of alkanol ammonium compounds and cationic amide compounds, present in an amount such that there is at least one molecule of cationic compound for at least one of the negatively charged functional groups on the dye, the pH of the ink composition being maintained in the acidic region below about 7. The ink composition prepared by the process of the invention eviaences minimal crusting and reduced evapo- ration loss of water. The solubility of acid ayes is increased in the acidic medium over that otherwise ob- tainable, due to the presence of the alkanol ammonium compound or cation amide compound. The ink composition prepared in accordance with the invention is suitably employed in any of the ink-jet printers commonly in use.

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