Process for preparing malonic esters

C - Chemistry – Metallurgy – 07 – C

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C07C 67/10 (2006.01) C07C 69/38 (2006.01)

Patent

CA 2294669

Malonic esters of the general formula: (see formula I) where R is C1-10 alkyl, C3-10-alkenyl or aryl-C1-4-alkyl, are prepared by reacting an alkali metal salt of malonic acid with a halide of the general formula R-X (II), where R is as defined above and X is chlorine, bromine or iodine, in the presence of water and a phase-transfer catalyst.

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