Process for preparing optically active citronellal

C - Chemistry – Metallurgy – 07 – C

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260/568.1

C07C 47/21 (2006.01) B01J 31/24 (2006.01) C07C 45/62 (2006.01)

Patent

CA 1117981

PRECIS DE LA DIVULGATION: Le citronellal optiquement actif est préparé par hydrogenation du néral ou du géranial en présence d'un catalyseur constitué par un complexe soluble dans le milieu réactionnel, formé à partir d'un dérivé du rhodium et d'une phosphine chirale. Le procédé de l'invention permet d'accéder au d-citronnellal intermédiaire de la synthèse du (-) (IS) menthol.

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