Process for preparing perfluoroalkenyl-sulfonyl fluorides

C - Chemistry – Metallurgy – 07 – C

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260/538.4

C07C 303/02 (2006.01) C07C 309/81 (2006.01)

Patent

CA 2015633

ABSTRACT OF THE DISCLOSURE A continuous process for preparing perfluoroalkenyl sulfonyl fluorides (I) Rf-CF=CF-S02F (I) wherein: Rf is selected from the group consisting of F and a perfluoroalkyl radical of from 1 to 9 carbon atoms is disclosed, in which as the starting compound a sultone (II) (II) Image is used. The starting compound is placed into contact with a reactant selected from the group consisting of oxides and carbonates of an element of the groups IA, IIA and IIB, and of the oxides of an element of the Groups IIIA and IVA of the Periodic Table of the Elements, and their mixtures, at a temperature comprised within the range of from 150 to 450°C, and the compound (I) is recovered from the reaction effluent.

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