Process for preparing perfluoropolyethers with bromo- or...

C - Chemistry – Metallurgy – 08 – G

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C08G 65/32 (2006.01) C08G 65/00 (2006.01) C08G 65/26 (2006.01)

Patent

CA 2203339

Process for preparing perfluoropolyethers with bromo- or iodo-containing end groups, respectively, by subjecting a peroxidic perfluoropolyether to thermal treatment, in absence of UV radiations, at temperatures from 120°C to 280°C in the presence of bromo- or iodo-containing compounds having, respectively, the following general formulas: T T'T" C Br wherein T,T',T" equal to or different from each other are selected from Br, F, H or R'f, wherein R'f is a perfluoroalkylic chain from 1 to 8 carbon atoms; R R'R"C I wherein R, R',R", equal to or different from each other can be I (iodine), H, F or R'f, wherein R'f has the meaning indicated above.

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