Process for preparing prostaglandin analogs using...

C - Chemistry – Metallurgy – 07 – C

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260/235.01, 260/

C07C 405/00 (2006.01) C07F 1/08 (2006.01) C07F 7/18 (2006.01)

Patent

CA 2040468

A process for preparing a prostaglandin derivative by reacting an alkyne with zirconocene chloride hydride to produce a zirconium intermediate which is reacted with an alkyllithium and a first copper reagent selected from R2Cu(CN)Li or the mixture CuCN and R2Li to produce a higher order cuprate complex intermediate and reacting the higher order cuprate complex intermediate with a cyclopentenone to produce the prostaglandin derivative having the general formula Image

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