Process for preparing sparingly soluble calcium sulphate...

C - Chemistry – Metallurgy – 01 – F

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C01F 11/46 (2006.01) C04B 11/02 (2006.01) C04B 11/05 (2006.01)

Patent

CA 2215854

The invention relates to a process for preparing sparingly soluble calcium sulphate anhydrite-II in which finely divided dry calcium sulphate dihydrate is dehydrated in a calcining unit by appropriate action of heat, is held at the calcination temperature under steam, and the calcined material is ground. During this process, the finely divided calcium sulphate dihydrate is heated to a temperature of from 580 to 650°C and is held at this temperature under steam with a partial steam pressure < 0.2 bar for an adequate residence time, in such a way that a phase mixture of predominantly sparingly soluble calcium sulphate anhydrite-II and a lower proportion of insoluble calcium sulphate anhydrite-II and calcium sulphate anhydrite-III is formed, the resultant phase mixture being ground to a Blaine specific surface area of > 4000 cm2/g.

L'invention concerne un procédé pour préparer de l'anhydrite-II (sulfate de calcium) faiblement soluble dans lequel du sulfate de calcium dihydraté sec finement pulvérisé est déshydraté dans un appareil de calcination par action appropriée de la chaleur et est maintenu à la température de calcination sous vapeur, après quoi la matière calcinée est pulvérisée. Durant ce procédé, le sulfate de calcium dihydraté finement pulvérisé est chauffé à une température variant de 580 à 650 degrés C et est gardé à cette température sous vapeur, à une pression partielle de vapeur < 0,2 bar, pendant une période de temps appropriée, de telle manière qu'il se forme un mélange de phases contenant une proportion prédominante d'anhydrite-II (sulfate de calcium) faiblement soluble et une proportion inférieure d'anhydrite-II insoluble et d'anhydrite-III, le mélange de phases résultant étant pulvérisé jusqu'à l'obtention d'une surface spécifique de Blaine > 4 000 cm2/g.

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