Process for producing 1,4-dienes

C - Chemistry – Metallurgy – 07 – C

Patent

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Details

C07C 11/02 (2006.01) C07C 2/02 (2006.01) C07C 2/04 (2006.01) C08F 2/60 (2006.01) C08F 36/04 (2006.01)

Patent

CA 2162120

Pure 1,4-dienes are produced at high rates of reaction by reacting a conjugated diene and an alpha monoolefin at a temperature below 70 °C in the presence of a catalyst comprising a 1,3-bis-(diphenylphosphino) propane ligand of Co(II)(acetylacetonate )2 or Co(II) (acetylacetonate)3 or CoCl2 in combination with a dialkylaluminum halide such as diethylaluminum chloride.

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