Process for producing 6-cyanomethyl-1,3-dioxane-4-acetic...

C - Chemistry – Metallurgy – 07 – D

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C07D 319/06 (2006.01) C07B 61/00 (2006.01) C07C 253/14 (2006.01) C07C 255/20 (2006.01)

Patent

CA 2329893

A process whereby 6-cyanomethyl-1,3-dioxane-4-acetic acid derivatives, which are important intermediates of an HMG coenzyme A reductase atorvastatin, can be industrially, easily and efficiently produced. This process comprises starting with a 3,5-dihydroxy-6-halohexane derivative, treating it with a cyaniding agent to thereby substitute the halogen atom with the cyano group (i.e., a cyanation reaction) and forming an acetal of a diol by using an acetal-forming agent in the presence of an acid catalyst (i.e., an acetal- formation reaction).

On décrit un procédé au moyen duquel il est possible de produire en grande quantité à la fois facilement et efficacement des dérivés d'acide acétique 6-cyanométhyl-1,3-dioxane-4 qui sont des intermédiaires importants d'une atorvastatine HMG coenzyme A -réductase. Ce procédé consiste à utiliser comme produit de départ un dérivé 3,5-dihydroxy-6-halohexane, à le traiter avec un agent cyanurant pour remplacer ainsi l'atome halogène par le groupe cyano (c'est-à-dire effectuer une réaction de cyanuration) et à former un acétal d'un diol à l'aide d'un agent formateur d'acétal en présence d'un catalyseur acide (c'est-à-dire effectuer une réaction de formation d'acétal).

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