Process for producing alcohols

C - Chemistry – Metallurgy – 07 – C

Patent

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260/638.5, 260/6

C07C 29/46 (2006.01) C07C 29/74 (2006.01)

Patent

CA 1042469

ABSTRACT OF THE DISCLOSURE A novel process for the production of unsaturated higher alcohols from conjugated dienes and aldehydes, and to compositions of matter obtained by the process. Unsaturated higher alcohols of variable chain length, as well as other oxygenated products are produced by contacting a conjugated diolefin with an aldehyde in the presence of a salt chelate or coordination compound of Pd or Pt and, if the ligand is not already present in the co- ordination compound, a ligand of the type YR3, wherein Y is phosphorous or arsenic and R is an alkyl group with 1-12 carbon atoms or an aryl or arylalkyl group with an equivalent or higher amount of carbon atoms.

120216

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