Process for producing .alpha.,.beta.-unsaturated aldehydes...

C - Chemistry – Metallurgy – 07 – J

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260/4, 260/7, 26

C07J 9/00 (2006.01) C07J 51/00 (2006.01) C07J 63/00 (2006.01) C07J 71/00 (2006.01)

Patent

CA 1138428

ABSTRACT OF THE DISCLOSURE .alpha.,.beta.-Unsaturated aldehydes and ketones are prepared by reaction of an arylseleninic anhydride with an aldehyde or ketone having at least one hy- drogen atom in the .alpha.-position which is or can be in the syn-configuration with respect to at least one hydrogen atom in the said .beta.-position. The ke-tones used as starting material especially include perhydrophenanthrene ketones such as steroid ketones and the arylseleninic anhydride used may for example be benzeneseleninic anhydride.

320620

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