Process for producing aromatic diols and their ether...

C - Chemistry – Metallurgy – 07 – C

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260/494.3, 260/6

C07C 39/08 (2006.01) C07C 37/055 (2006.01) C07C 41/26 (2006.01) C07C 43/23 (2006.01) C07C 45/71 (2006.01) C07C 49/84 (2006.01) C07C 69/14 (2006.01)

Patent

CA 1264764

Abstract An aromatic diol, e.g. hydroquinone, or a monoalkyl ether of an aromatic diol, e.g. the monomethyl ether of hydro- quinone, is produced by transesterifiying a carboxylate ester of said aromatic diol or monoalkyl ether with an alcohol or phenol such as ethanol. A newly-formed ester such as ethyl acetate is co-produced by the reaction. The carboxylate ester is preferably produced by subjecting an aromatic ketone con- taining a hydroxy or alkoxy radical on the aromatic ring, e.g. 4-hydroxyacetophenone, to a Baeyer-Villiger oxidation.

498418

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