C - Chemistry – Metallurgy – 07 – C
Patent
C - Chemistry, Metallurgy
07
C
260/494.3, 260/6
C07C 39/08 (2006.01) C07C 37/055 (2006.01) C07C 41/26 (2006.01) C07C 43/23 (2006.01) C07C 45/71 (2006.01) C07C 49/84 (2006.01) C07C 69/14 (2006.01)
Patent
CA 1264764
Abstract An aromatic diol, e.g. hydroquinone, or a monoalkyl ether of an aromatic diol, e.g. the monomethyl ether of hydro- quinone, is produced by transesterifiying a carboxylate ester of said aromatic diol or monoalkyl ether with an alcohol or phenol such as ethanol. A newly-formed ester such as ethyl acetate is co-produced by the reaction. The carboxylate ester is preferably produced by subjecting an aromatic ketone con- taining a hydroxy or alkoxy radical on the aromatic ring, e.g. 4-hydroxyacetophenone, to a Baeyer-Villiger oxidation.
498418
Celanese Corporation
Hilton Charles B.
Smart & Biggar
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