C - Chemistry – Metallurgy – 07 – C
Patent
C - Chemistry, Metallurgy
07
C
C07C 69/54 (2006.01) C07C 29/84 (2006.01) C07C 31/02 (2006.01) C07C 51/44 (2006.01) C07C 57/07 (2006.01) C07C 67/08 (2006.01) C07C 67/54 (2006.01) C07C 67/60 (2006.01)
Patent
CA 2192264
An improved process for producing n-butyl acrylate in high yield and high purity substantially free of acrylic acid, incorporates one or more of the following new process components in an acid-catalyzed esterification process for producing n- butyl acrylate: 1. A hydrolytic recovery component, wherein heavy end adducts produced during the acid-catalyzed esterification are hydrolyzed, recovered, andrecycled as valuable reactants from a hydrolytic recovery unit (HRU); 2. A cracking reactor component, preferably used with the HRU, wherein additional valuable reactants are recovered and recycled after treatment in the cracking reactor; and 3. A new distillative component, wherein a crude n-butyl acrylate stream is efficiently distilled in an aqueous mode through an acrylic acid separation column, thereby providing n-butyl acrylate substantially free of acrylic acid and in high yield. The first two components also are applicable to acid-catalyzed processes producing C1 to C4 alkyl acrylates. A continuous process producing n-butyl acrylate incorporating all new process components also is disclosed.
Bauer William Jr.
Chapman Josefina Tseng
Mirabelli Mario Giuseppe Luciano
Venter Jeremia Jesaja
Bauer William Jr.
Chapman Josefina Tseng
Gowling Lafleur Henderson Llp
Mirabelli Mario Giuseppe Luciano
Rohm And Haas Company
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