Process for producing ceramic powders, especially titanium...

C - Chemistry – Metallurgy – 01 – G

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C01G 23/07 (2006.01)

Patent

CA 2288438

A gas phase process for the production of titanium dioxide powders having well- controlled crystalline and surface area characteristics is disclosed. In this process, which is preferably carried out in a laminar diffusion flame reactor, vapor phase TiCI4 and oxygen are mixed in a reaction area which is heated externally. The titanium dioxide powder formed is then collected. It is preferred that the heat source used be a hydrocarbon fueled (e.g., methane) flame. Optionally, a vapor phase dopant (such as SiCl4) may be added to tire reaction mixture to desirably affect flee physical properties of the titanium dioxide produced. In a particularly preferred embodiment, a corona electric field is positioned across the area where the combustion reaction takes place (i.e., the reaction area). High anatase, high surface area titanium dioxide powders made by this process are excellent photocatalysis. The products of this process and the use of those products as photocatalysis are also disclosed. This process is also useful for producing other ceramic powders (such as silicon dioxide and tin oxide), as well as pure metallic or alloy powders.

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