Process for producing dimethylcarbonate

C - Chemistry – Metallurgy – 07 – C

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260/466.9

C07C 69/96 (2006.01) B01J 23/72 (2006.01) B01J 27/10 (2006.01) C01B 3/50 (2006.01) C07C 67/36 (2006.01) C07C 68/00 (2006.01) C07C 68/04 (2006.01) C07C 69/00 (2006.01)

Patent

CA 1158663

ABSTRACT OF THE DISCLOSURE: A process for preparing dimethylcarbonate by reacting methanol with mixtures of carbon monoxide and oxygen which also contain hydrogen. The catalyst is constituted by a salt of a metal of groups IB, IIB or VIII of the periodic system, dissolved or dispersed in the reac- tion medium. It has been found that the hydrogen does not interfere in the reaction, so that a hydrogen-enriched gaseous mixture (synthesis gas) is withdrawn from the reactor. It is therefore particularly advantageous in that it produces dimethylcarbonate and at the same time provides hydrogen-enriched synthesis gas.

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