Process for producing ethanol and n-propanol from methanol

Details Process for producing ethanol and n-propanol from methanol Process for producing ethanol and n-propanol from methanol

C - Chemistry, Metallurgy

07

C

260/639

C07C 31/02 (2006.01) B01J 31/24 (2006.01) B01J 31/30 (2006.01) C07C 29/32 (2006.01)

Patent

CA 1189538

Abstract Of Disclosure A method for the production of ethanol or propanol comprising the reaction of methanol with carbon monoxide and hydrogen in the presence of a catalyst. The catalyst contains a cobalt compound, a ruthenium compound, iodine or an iodide, and a bi-dentate organic phosphine or phosphite. The reaction is carried out at 150° to 250°C, 200 to 600 bars, and in the presence of 5 to 25% by weight of water, based on the methanol. -1-

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