C - Chemistry – Metallurgy – 08 – F
Patent
C - Chemistry, Metallurgy
08
F
C08F 210/18 (2006.01) C08F 2/38 (2006.01) C08F 4/68 (2006.01) C08F 232/08 (2006.01) C08F 236/20 (2006.01)
Patent
CA 2292387
A process for production of an ethylene-propylene-dime-methylene (EPDM) tetrapolymer having long chain branching is described. The process comprises the step of polymerizing a monomer mixture comprising ethylene, propylene, a first diolefin monomer containing one polymerizable double bond (preferably ENB) and a second diolefin containing two polymerizable double bonds (preferably VNB) in the presence of a catalyst system. The catalyst system comprises: a catalyst comprising a compound containing vanadium +3 with the proviso that the compound does not comprise a halogen directly bound to the vanadium; a halogenated organoaluminum cocatalyst having a halogen to aluminum molar ratio in the range of from about 1 to about 2; and an activator. The branched polymer product of the present process exhibits a molecular weight distribution of less than about 3.5 and improved rheological properties and enhanced processability characteristics.
Bender Harald
Padliya Dilipkumar
Zahalka Hayder A.
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