Process for producing purified terephthalic acid

C - Chemistry – Metallurgy – 07 – C

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C07C 51/215 (2006.01) C07C 51/487 (2006.01) C07C 63/26 (2006.01)

Patent

CA 2046163

In a process for producing purified terephthalic acid which comprises catalytically oxidizing p-xylene in liquid phase to produce crude terephthalic acid containing 4-carboxybencaldehyde as a main impurity therein, and treating the crude terephthalic acid with hydrogen in the presence of a hydrogenation catalyst in a reaction vessel, thereby to produce purified terephthalic acid containing 4-carboxybenzaldehyde in an amount of fixed range in a stationary manner, there is provided an improvement which makes it possible for the treatment to reach the stationary state promtly after partial exchange of deactivated catalyst for a new one. The improvement comprises feeding into the reactor crude terephthalic acid which contains 4-carboxy-benzaldehyde in an amount larger than that in the stationary state of the treatment, and treating the terephthalic acid until the treatment reaches the stationary state.

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