C - Chemistry – Metallurgy – 07 – C
Patent
C - Chemistry, Metallurgy
07
C
C07C 51/215 (2006.01) C07C 51/487 (2006.01) C07C 63/26 (2006.01)
Patent
CA 2046163
In a process for producing purified terephthalic acid which comprises catalytically oxidizing p-xylene in liquid phase to produce crude terephthalic acid containing 4-carboxybencaldehyde as a main impurity therein, and treating the crude terephthalic acid with hydrogen in the presence of a hydrogenation catalyst in a reaction vessel, thereby to produce purified terephthalic acid containing 4-carboxybenzaldehyde in an amount of fixed range in a stationary manner, there is provided an improvement which makes it possible for the treatment to reach the stationary state promtly after partial exchange of deactivated catalyst for a new one. The improvement comprises feeding into the reactor crude terephthalic acid which contains 4-carboxy-benzaldehyde in an amount larger than that in the stationary state of the treatment, and treating the terephthalic acid until the treatment reaches the stationary state.
Taniguchi Norio
Yamane Hiroshi
Mitsui Chemicals Inc.
Smart & Biggar
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