Process for production of gasoline blending stock

C - Chemistry – Metallurgy – 07 – C

Patent

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260/639, 260/648

C07C 29/34 (2006.01) C07C 31/12 (2006.01) C07C 43/04 (2006.01)

Patent

CA 1275656

ABSTRACT A process for producing a gasoline blending stock of methyl tertiary butyl ether and tertiary butyl alcohol wherein a first catalytic etherification of isobutene and methanol produces methyl tertiary butyl ether and unreacted methanol. The etherification product including isobutene and remaining methanol is reacted with water and fresh iso- butene in a second catalytic reaction where both etherifica- tion and hydration occur. This essentially exhausts the methanol while the hydration reaction to tertiary butyl alcohol prevents undesired side reactions.

552609

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