Process for production of sterically stabilised non-aqueous...

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400/3028

B01F 17/42 (2006.01) C09D 3/48 (1980.01)

Patent

CA 1164131

V. 31077 ABSTRACT OF DISCLOSURE A process is described for making sterically stabilised non-aqueous dispersions of polymer microparticles, in which (1) monomers including at least one crosslinking monomer are polymerised in an aqueous medium at a temperature at least 10° higher than the glass transition temperature of the polymer to be formed, in the presence of a block or graft copolymer stabilising agent containing in the molecule, as the component solvated by the aqueous medium, a polymer chain derived from a polyethylene glycol of molecular weight at least 1000, under conditions such that there is at no time present a separate monomer phase and (2) the microparticles thus obtained are transferred into a non-aqueous medium which is capable of dissolving the polyethylene glycol in question, when the latter is in the non-hydrated state, to the extent of at least 10% by weight at room temperature. The microparticles are of value for incorporation into coating compositions the main film-forming constituent of which is compatible with the polyethylene glycol- derived stabilising chains of the particles.

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