Process for purification of the alkali metal salt of...

C - Chemistry – Metallurgy – 07 – C

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260/530.3

C07C 303/44 (2006.01) C07C 309/22 (2006.01)

Patent

CA 1145770

PROCESS FOR PURIFICATION OF THE ALKALI METAL SALT OF SULFONATED UNSATURATED ALIPHATIC CARBOXYLIC ACID Abstract of the Disclosure A process for purifying a salt of sulfonated un- saturated aliphatic carboxylic acid, and in particular, a salt of sulfonated oleic acid wherein unreacted saturated fatty acid impurities are removed by the steps of diluting the mixture of the salt of sulfonated acid and impurities with an amount of water sufficient to provide an aqueous solution containing from about 5 to about 30 percent by weight of the salt, adding a synthetic aliphatic or isoparaffinic hydro- carbon solvent having a boiling point in the range of about 150°C to about 260°C in an amount such that the hydrocarbon is present in about 10 to about 50 percent by volume, agitating the mixture for a time sufficient to provide an intimate contact of the solvent with the impurities, holding the mixture in a quiescent state for a time sufficient to allow the water and solvent to separate into layers, and then drawing off the purified aqueous layer. The aqueous layer thus extracted is preferably used in detergent formulations suitable for cleaning containers that will contact food, and the purified salt of oleic acid or the like provides improved products for use in this and other applications.

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