Process for radical polymerization of acid ph vinyl chloride...

C - Chemistry – Metallurgy – 08 – F

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C08F 2/18 (2006.01) C08F 4/00 (2006.01) C08F 14/06 (2006.01)

Patent

CA 2133914

La température du milieu de polymérisation du chlorure de vinyle à l'intervention d'initiateurs oléosolubles est régulée essentiellement par injection directe et modulée d'une quantité efficace d'un inhibiteur inorganique fort de la polymérisation radicalaire ou d'un précurseur, choisis avantageusement parmi l'iode et le monoxyde d'azote, ainsi que parmi les iodures et les nitrites des métaux alcalins, précurseurs respectifs de l'iode et du monoxyde d'azote. Le procédé conduit à une amélioration significative de la productivité des réacteurs.

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