Process for recovering uranium from wet process phosphoric acid

C - Chemistry – Metallurgy – 22 – B

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C22B 60/02 (2006.01)

Patent

CA 1103037

ABSTRACT OF THE DISCLOSURE An improvement in the process for the recovery of uranium from a phosphoric acid solution derived from the acidification of uraniferous phosphate ores including the steps of reducing the uranium in the phosphoric acid solution to the uranous form and contacting the resulting solution with a liquid ion exchange agent which is a mixture of a mono and disubstituted phenyl esters of orthophosphoric acid dissolved in an inert organic diluent, to effect recovery of the uranium with the liquid ion exchange agent, the improvement being maintaining the proper ratio of the mono and di-components of the liquid ion exchange mixture which comprises removing dissolved and entrained uranium process organics from the raffinate resulting from said liquid ion exchange step and recycling the removed organics to said liquid ion exchange step.

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