Process for reduction of carbon dioxide with organometallic...

C - Chemistry – Metallurgy – 07 – C

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C07C 51/00 (2006.01) C07B 61/00 (2006.01) C07C 53/02 (2006.01)

Patent

CA 2539174

Carbon dioxide and water are mixed with an organometallic complex represented by general formula (1) below (see formula 1) where R1, R2, R3, R4, R5, and R6 independently represent a hydrogen atom or a lower alkyl group, M represents an element that can be coordinated to the benzene ring, X1 and X2 represent nitrogen-containing ligands, X3 represents a hydrogen atom, a carboxylic acid residue, or H2O, X1 and X2 may be bonded to each other, Y represents an anion species, K represents a valency of a cation species, L represents a valency of an anion species, K and L independently represent 1 or 2, and K, m, L, and n are related to one another by K x m = L x n. This makes it possible to directly reduce carbon dioxide in water.

On effectue une réduction directe du dioxyde de carbone dans de l'eau en mélangeant le dioxyde de carbone avec l'eau et un complexe organométallique représenté par la formule générale (1), dans laquelle R<1>, R<2>, R<3>, R<4>, R<5> et R<6> sont chacun indépendamment hydrogène ou alkyle inférieur; M est un élément pouvant se conjuguer à un noyau benzène; X<1> et X<2> sont chacun un ligand azoté; X<3> est hydrogène, un résidu d'acide carboxylique, ou H2O; X<1> et X<2> peuvent être liés l'un à l'autre; Y est un anion; K représente la valence du cation et L représente la valence de l'anion, et K et L sont chacun indépendamment 1 ou 2 et satisfont la relation: K x m = L x n.

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