Process for removal of nitrogen containing contaminants from...

C - Chemistry – Metallurgy – 10 – G

Patent

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C10G 67/06 (2006.01) B01J 20/16 (2006.01) B01J 21/08 (2006.01) C10G 25/00 (2006.01) C10G 45/02 (2006.01)

Patent

CA 2510986

The present invention is directed to the removal of nitrogen and sulfur containing impurities from high molecular weight petroleum feedstock obtained from fluid cracking catalyst or distillation zone of a petroleum treatment plant. The present process comprises first treating C12 and higher hydrocarbon petroleum feedstock having nitrogen and sulfur containing compounds therein with a porous, particulate adsorbent comprising a silica matrix having an effective amount of metal atoms therein to cause the adsorbent to have Lewis acidity of at least 500 ~mol/g and then treating the resultant feedstock to catalytic hydrodesulfurization to produce a hydrocarbon fuel having low sulfur and nitrogen content.

L'invention concerne la suppression d'impuretés contenant de l'azote et du soufre dans une charge d'alimentation de pétrole de poids moléculaire élevé obtenue à partir d'un catalyseur de craquage de fluide ou d'une zone de distillation d'une installation de traitement de pétrole. Le procédé de l'invention consiste à traiter du C¿12? et une charge d'alimentation de pétrole d'hydrocarbures supérieurs présentant des composés contenant de l'azote et du soufre, à l'aide de matière particulaire poreuse comprenant une matrice en silice présentant une quantité efficace d'atomes métalliques pour permettre à cette matière absorbante de présenter une acidité de Lewis d'au moins 500 ?mol/g, puis à traiter la charge d'alimentation obtenue en hydrodésulfurisation catalytique pour produire un combustible hydrocarbure présentant une faible teneur en soufre et en azote.

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