Process for selective liquid-liquid extraction of germanium

C - Chemistry – Metallurgy – 22 – B

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C22B 41/00 (2006.01)

Patent

CA 1179145

ABSTRACT OF THE DISCLOSURE A process for selective liquid-liquid extraction of germanium from an aqueous acidic liquor containing, be- sides germanium, at least one other metal selected from the group which comprises cadmium, zinc, cobalt, iron, ar- senic and nickel. This process includes extracting germa- nium from said aqueous liquor by contacting said liquor with an organic medium containing a diluent and an extrac- tant, said diluent being immiscible with said aqueous li- quor. The major part of germanium passes from said aqueous liquor to an organic phase which is subsequently submitted to a stripping step by contacting with an alkaline medium, with formation of an aqueous phase containing the major part of germanium from said aqueous liquor.

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