Process for selective oxidation of primary alcohols and...

C - Chemistry – Metallurgy – 12 – P

Patent

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C12P 1/00 (2006.01) C07C 45/29 (2006.01) C07C 45/32 (2006.01) C07C 45/38 (2006.01) C07C 45/39 (2006.01) C07H 1/00 (2006.01) C07H 3/00 (2006.01) C07H 5/04 (2006.01) C08B 1/00 (2006.01) C08L 1/00 (2006.01) C08L 3/00 (2006.01) C12P 7/24 (2006.01) C12P 13/00 (2006.01) C12P 19/00 (2006.01) C12P 19/04 (2006.01)

Patent

CA 2362717

A process for producing aldehydes, and/or carboxylic acids is described, in which a primary alcohol, especially a carbohydrate, is oxidised using a catalytic amount of a nitrosonium compound obtained by oxidising a nitroxyl compound in the presence of an enzyme compound capable of oxidation. Further described are oxidised carbohydrates containing at least 1 cyclic monosaccharide chain group carrying a carbaldehyde group per 25 monosaccharide units and per molecule.

L'invention se rapporte à un procédé de production d'aldéhydes et/ou d'acides carboxyliques, selon lequel un alcool primaire, notamment un glucide, est oxydé à l'aide d'une quantité catalytique d'un composé nitrosonium obtenu par oxydation d'un composé nitroxyle en présence d'un enzyme susceptible d'oxyder. L'invention se rapporte en outre à des glucides oxydés contenant au moins un groupe à chaîne monosaccharide cyclique portant un groupe carbaldéhyde pour 25 unités monosaccharide et par molécule.

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