Process for separately recovering zinc and lead values from...

B - Operations – Transporting – 03 – D

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53/324, 53/340

B03D 1/06 (2006.01) B03D 1/02 (2006.01)

Patent

CA 1216157

ABSTRACT OF THE DISCLOSURE A process for separately recovering zinc and lead values from zinc and lead containing sulphidic ore which also contains iron comprises subjecting ground ore to a first flotation step to float an initial lead concentrate containing zinc and produce zinc and iron containing tailings. The zinc and iron containing tailings are subjected to a second flotation step to float an initial zinc concentrate containing iron and also produce tailings. The initial zinc concentrate is subjected to a third flotation step to float a further zinc concentrate containing iron and also pro- duce zinc and iron containing tailings. The zinc and iron containing tailings from the third flotation step and at least a lead and zinc containing portion of the initial lead concentrate are leached in a first leach step under oxidizing conditions at a temperature in the range of from about 130 to about 170°C in aqueous sulphuric acid solution with a stoichiometric excess of sulphuric acid relative to the zinc content of from about 50 to about 150% so as to give a terminal acidity of from about 50 to about 80 g/L to produce a lead-containing residue and a first leach solution containing zinc and iron. The lead con- taining residue is separated from the first leach solu- tion and the first leach solution is treated with the further zinc concentrate or calcine produced therefrom by roasting to dissolve zinc therefrom and precipitate a substantial amount of dissolved iron, thereby pro- ducing an iron containing residue and a second leach solution containing zinc. The iron containing residue is separated from the second leach solution, and the second leach solution is treated to recover zinc.

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