Process for synthesizing perfluoroalkyl iodides

C - Chemistry – Metallurgy – 07 – C

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C07C 19/08 (2006.01) C07C 17/275 (2006.01) C07C 17/278 (2006.01)

Patent

CA 2121182

PRECIS DE LA DIVULGATION: L'invention concerne un procédé continu de prépa- ration des iodures de perfluoroalkyle par télomérisation thermique en phase gazeuse du tétrafluoroéthylène par l'iodure de pentafluoroéthyle ou d'heptafluoroisopropyle dans un réacteur tubulaire. Pour améliorer la sélectivité en un télomère de rang désiré, on recycle les télomères de rang inférieur en au moins un point du réacteur situé entre le vingtième et les trois quarts de la longueur du tube.

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