Process for the addition of a chlorinated methane containing...

Details Process for the addition of a chlorinated methane containing... Process for the addition of a chlorinated methane containing...

C - Chemistry, Metallurgy

07

C

260/663.1

C07C 19/00 (2006.01)

Patent

CA 1071657

PROCESS FOR THE ADDITION OF A CHLORINATED METHANE CONTAINING AT LEAST THREE CHLORINE ATOMS TO AN ETHYLENICALLY UNSATURATED HYDROCARBON Abstract An addition product of a chlorinated methane containing at least 3 chlorine atoms and an ethylenically unsaturated hydrocarbon is prepared by heating at about 70° to about 250° C. in the presence of a manganese compound in which the manganese has a valence of at least 3 as a radical initiator, and a compound containing a carbonyl group and an alpha-hydrogen atom the free ligands of which compounds are at either side linked to a carbon atoms, such as an aliphatic ketone. The products so obtained are useful as high boiling solvents for waxes and hydrocarbons and as free-proofing compounds.

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