Process for the amionic polymerisation of acrylic monomers,...

C - Chemistry – Metallurgy – 08 – F

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96/252, 402/374

C08F 20/10 (2006.01) C09D 5/32 (2006.01) C09D 133/06 (2006.01) G03F 7/039 (2006.01)

Patent

CA 1310155

PRECIS DE DIVULGATION Procédé de polymérisation de monomères acryliques et éventuellement de comonomères vinyliques à l'aide d'un amorceur de formule R - M (I) dans laquelle M désigne un métal choisi parmi les métaux alcalins et alcali- noterreux et R désigne un radical alkyle à chaîne droite ou ramifiée conte- nant 2 à 6 atomes de carbone ou un radical aryle. On effectue la polymerisation en présence d'un additif constitué d'un com- plexant macrocyclique non azoté. Application à l'obtention de polymères acryliques possèdant une distribution étroite des masses moléculaires.

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