Process for the carbonylation of an acetylenically...

C - Chemistry – Metallurgy – 07 – C

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C07C 69/54 (2006.01) C07C 51/14 (2006.01) C07C 57/04 (2006.01) C07C 67/38 (2006.01)

Patent

CA 2178739

A process capable of the low temperature carbonylation of an acetylenically unsaturated compound with carbon monoxide in the presence of an allenically unsaturated compound using a catalytic system, which is at least tolerant of the allenically unsaturated compound, formed from a) a palladium compound; b) a protonic acid; c) an organic phosphine of form (I), wherein R1 is an optionally substituted aryl group; R2 and R3 are joined to form an optionally substituted cyclic moiety comprising at least one optionally substituted alkylene group.

L'invention se rapporte à un procédé apte à effectuer la carbonylation à basse température d'un composé acétyléniquement insaturé avec un monoxyde de carbone en présence d'un composé alléniquement insaturé au moyen d'un système catalytique, et qui au moins tolère la présence du composé alléniquement insaturé obtenu à partir: a) d'un composé de palladium; b) d'un acide protonique; c) d'une phosphine organique de la formule (I) dans laquelle R?1¿ représente un groupe aryle éventuellement substitué; R?2¿ et R?3¿ sont réunis pour former une fraction cyclique éventuellement substituée comprenant au moins un groupe alcylène éventuellement substitué.

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