Process for the catalytic hydrogenolysis of p- substituted...

Details Process for the catalytic hydrogenolysis of p- substituted... Process for the catalytic hydrogenolysis of p- substituted...

C - Chemistry, Metallurgy

07

C

260/645.4

C07C 43/205 (2006.01) C07C 41/28 (2006.01) C07C 43/257 (2006.01)

Patent

CA 1184570

ABSTRACT OF THE DISCLOSURE Disclosed is a process for catalytic hydro- genolysis of p-substituted benzaldehyde-dialkyl-acetals of the general formula Image in which R is an alkyl group, an unsubstituted or sub- stituted aryl group or an unsubstituted or substituted aralkyl group, by means of a catalyst system composed of cobalt carbonyl and at least one nitrogen-containing heterocyclic compound, such as pyridine, pyrrole, pyrroli- done or piperidine and a hydrogen/carbon monoxide mixture to give the corresponding p-substituted benzyl alkyl ether derivatives.

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