Process for the catalytic hydroxylation of, saturated or...

C - Chemistry – Metallurgy – 07 – B

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C07B 41/02 (2006.01) C07C 29/48 (2006.01) C07C 31/125 (2006.01)

Patent

CA 2407408

A process for hydroxylating aliphatic compounds under catalytic distillation conditions to provide alcohols is provided. The aliphatic compound is contacted, in a distillation column reactor, with an oxidation catalyst and an oxidant under conditions effective to hydroxylate the aliphatic compound while maintaining at least a portion of the aliphatic compound in a liquid phase and separating the hydroxylated product from the un-reacted aliphatic compound.

L'invention concerne un procédé pour l'hydroxylation de composés aliphatiques dans des conditions de distillation catalytique pour produire des alcools. Ce procédé consiste à mettre en contact le composé aliphatique, dans un réacteur à colonne de distillation, avec un catalyseur d'oxydation et un oxydant dans des conditions provoquant l'hydroxylation du composé aliphatique, tout en maintenant au moins une partie du composé aliphatique dans une phase liquide et en séparant le produit hydroxylé du composé aliphatique n'ayant pas réagi.

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