Process for the cleavage of alkyl tert-alkyl ethers into...

C - Chemistry – Metallurgy – 07 – C

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C07C 11/09 (2006.01) C07C 1/20 (2006.01) C07C 11/10 (2006.01) C07C 29/00 (2006.01) C07C 29/10 (2006.01) C07C 31/02 (2006.01)

Patent

CA 2345520

The invention relates to a process for the cleavage of alkyl tert-alkyl ethers into the corresponding isoolefins and alkanols by acid-catalyzed reactive distillation, wherein the reactive distillation apparatus has, in an upward direction, a bottom zone, at least one distillation zone and a reaction zone and the alkyl tert-alkyl ether is fed into the reaction zone via an azeotrope of the alkyl tert-alkyl ether and the corresponding alkanol. The process is suitable for the cleavage of primary, secondary and tertiary alkyl tert-alkyl ethers, in particular MTBE.

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