Process for the conversion of a terminal carbon- carbon...

Details Process for the conversion of a terminal carbon- carbon... Process for the conversion of a terminal carbon- carbon...

C - Chemistry, Metallurgy

07

C

260/585.2, 260/5

C07C 45/34 (2006.01) C07C 49/04 (2006.01)

Patent

CA 1243041

A PROCESS FOR THE CONVERSION OF A TERMINAL CARBON-CARBON DOUBLE BOND OF AN OLEFINIC HYDROCARBON TO CARBONYL GROUPS ABSTRACT OF THE DISCLOSURE Terminal carbon-carbon double bonds of olefinic hydrocarbons are converted to carbonyl groups by reacting the olefin with oxygen in the presence of (a) a catalyst comprising (i) one or more of the metals palladium, rhodium, ruthenium or iridium, and (ii) copper, (b) a diluent comprising two liquid phases, and (c) a surfactant, provided that when the metal is palladium no alkali or alkaline earth metal is present and the surfactant is dodecyltrimethylammonium chloride or bromide.

437635

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