Process for the conversion of an alkane to a mixture of an...

Details Process for the conversion of an alkane to a mixture of an... Process for the conversion of an alkane to a mixture of an...

C - Chemistry, Metallurgy

07

C

260/583.3, 260/5

C07C 31/12 (2006.01) B01J 23/34 (2006.01) B01J 23/745 (2006.01) B01J 31/18 (2006.01) C07C 29/132 (2006.01) C07C 29/48 (2006.01) C07C 35/08 (2006.01) C07C 45/28 (2006.01) C07C 49/303 (2006.01)

Patent

CA 1215388

Case 5266/5267 (2) ABSTRACT OF THE DISCLOSURE A mixture of the alcohol and ketone derivatives of alkanes is produced by reacting the alkane with a hydrocarbyl hydroperoxide, eg t-butyl hydroperoxide, at ambient or elevated temperature and pressure in the presence as catalyst of an iron or manganese square planar complex having heterocyclic nitrogen-donor ligands, eg a porphyrin or phthalocyanine complex, which complex has either no axial ligands, eg the lower valency or cationic complex, or an axial ligand which is non-coordinating or weakly-coordinating.

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