Process for the decomposition and decontamination of organic...

C - Chemistry – Metallurgy – 07 – C

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C07C 25/18 (2006.01) C07D 319/24 (2006.01) C10M 105/06 (2006.01) A62D 3/00 (2006.01)

Patent

CA 1250303

- 1 - Abstract: PROCESS FOR THE DECOMPOSITION AND DECONTAMINATION OF ORGANIC SUBSTANCES AND HALOGENATED TOXIC MATE- RIALS" A method for the decomposition of an halogenated organic compound is described which comprises reac ting the compound with a reagent which consists of a) at least one member which is a polyethylenegly- col, Nixolen(R), an alcohol or a polyhydroxy com- pound, b) a base, and c) an oxidizing agent or a source of radicals, in the absence of oxygen. The method is applicable to the decontamination of mineral oils and soil contaminated with polychlorobi phenyls, polychlorodibenzofurans, polychlorodibenzo dioxins, DDT and other halogenated organic compo- unds. The different possible formulations of such rea- gents allow the preparation of stable reactive mix- ture, which can be either liquid or solid; the li- quid reagents are particularly suitable for the de contamination of porous surfaces such as cement, gres, asphalt and for the decontamination of parts of plants contaminated by PCBs. The use of microwaves during the decontamination process proved to be particularly advantageous.

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