Process for the electrocarboxylation of carbonyl compounds,...

C - Chemistry – Metallurgy – 25 – B

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204/43.5

C25B 3/00 (2006.01) C25B 3/04 (2006.01)

Patent

CA 1273601

ABSTRACT A process for the electrocarboxylation of carbonyl compounds, for producing ?-hydroxycarboxylic acids by means of the reaction: Image The electrolysis of the carbonyl compound is conducted in a diaphragm-less cell with a soluble metal anode in the presence of a support electrolyte and an organic solvent. into which carbon dioxide is bubbled. The complex salt obtained by the electrolysis is precipitated by treatment with a solvent, and is then separated and hydrolysed to obtain the required acid.

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