Process for the electrochemical preparation of catalysts...

B - Operations – Transporting – 01 – J

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B01J 31/24 (2006.01) B01J 37/34 (2006.01)

Patent

CA 2240445

The present invention relates to an electrochemical process for the preparation of compounds which can be used as catalysts. The disclosed compounds comprise more specifically a transition metal with an oxidation degree of 0 or 1 associated to at least one monodentate or bidentate hydrosoluble phosphine. The process for the electrochemical synthesis of catalysts comprises the treatment by electrolysis of an aqueous solution containing at least a compound of a transition metal and a monodentate or bidentate hydrosoluble phosphine placed within the cathode compartment of an electrolysis cell of an electrolyser.

La présente invention concerne un procédé électrochimique de préparation de composés pouvant être utilisés comme catalyseurs. Les composés visés comportent plus spécifiquement au moins un métal de transition au degré d'oxydation 0 ou 1 associé à au moins une phosphine hydrosoluble monodentate ou bidentate. Le procédé de synthèse électrochimique des catalyseurs consiste à traiter par électrolyse une solution aqueuse contenant au moins un composé d'un métal de transition et une phosphine hydrosoluble monodentate ou bidentate, placée dans le compartiment cathodique d'une cellule d'électrolyse d'un électrolyseur.

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