Process for the exchange of hydrogen isotopes between...

B - Operations – Transporting – 01 – J

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23/285, 252/91

B01J 23/42 (2006.01) B01D 59/32 (2006.01) C01B 5/02 (2006.01)

Patent

CA 1063587

ABSTRACT OF DISCLOSURE A process and catalyst for the exchange of hydrogen isotopes between streams of gaseous hydrogen and liquid water is described, wherein the streams are brought into contact with one another and a catalyst assembly at a temperature in the range 273 to 573K, the catalyst assembly comprises an inherently hydrophobic, porous, polytetrafluoroethylene matrix and partially platini- zed carbon particles in the weight ratio of 0.5:1 to 6:1 of polytetrafluoroethylene to partially platinized high surface area carbon particles. The inherently hydrophobic, porous polytetrafluoroethylene matrix allows the catalytically acti- ve metal to catalyze the hydrogen isotope exchange reaction between hydrogen gas and water vapour in the presence of li- quid water while retarding loss of activity of the catalyti- cally active metal by contact of the metal catalyst with li- quid water. This catalyzed chemical isotope exchange proceeds simultaneously with isotope exchange from water vapour to li- quid water by a non-catalyzed, physical evaporation and con- densation exchange reaction. The efficient coupling of the two isotopic transfer steps which results in a rapid overall isotopic exchange between hydrogen and liquid water without a pronounced loss of activity of the catalyst is dependent upon the weight ratio of the catalytically active platinized carbon to the polytetrafluoroethylene matrix being in the range 0.5:1 to 6:1 and for best results preferably in the range 1:1 to 3:1.

255751

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