Process for the hydrogenolysis of the acetals and ketals of...

Details Process for the hydrogenolysis of the acetals and ketals of... Process for the hydrogenolysis of the acetals and ketals of...

C - Chemistry, Metallurgy

07

C

260/636.4, 260/6

C07C 43/10 (2006.01)

Patent

CA 1100531

Abstract of the Disclosure An improved process for the hydrogenolysis of acetals and ketals of organic hydrocarbons is described. The improvement resides in using a catalyst system including a halide of a Group III A element and a supported platinum or rhodium hydrogenation catalyst or combination thereof, thus enabling the process to be practiced at a temperature of from about -15°C. to about 125°C. and a pressure of from about 50 psia to about 2000 psia. The preferred Group III A halides are boron trifluoride and aluminum trichloride.

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