Process for the improved production of (meth) acrylic acid...

C - Chemistry – Metallurgy – 07 – C

Patent

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260/481.9

C07C 67/08 (2006.01) C07C 69/54 (2006.01) C08G 65/332 (2006.01)

Patent

CA 2006433

ABSTRACT OF THE DISCLOSURE A process for the production of (meth)acrylic acid esters of polyhydric alcohols by reaction of the reactants in the presence of an acidic esterification catalyst with addition of a substituted phenolic compound, more particularly di-tert.-butyl hydroquinone, as a polymerization inhibitor. In the new process the reaction mixtures used are liquid at room temperature and are at least substantially free from solvents an/or azeotropic entraining agents, and the water of condensation formed is removed from the gas phase of the reaction zone.

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