Process for the manufacture of acetone from isobutyraldehyde

C - Chemistry – Metallurgy – 07 – C

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260/586.7

C07C 49/08 (2006.01) B01J 23/06 (2006.01) B01J 23/80 (2006.01) C07C 45/33 (2006.01)

Patent

CA 1096885

ABSTRACT An improved process for the manufacture of acetone by the selec- tive catalytic decarbonylation of isobutyraldehyde is disclosed. The process involves passing a gaseous mixture containing isobutyraldehyde and oxygen at elevated temperature over a zinc oxide-supported catalyst containing copper oxide and from 2.5 to 25 per cent by weight of graphite, based on the ready- to-use catalyst. The conversion of isobutyraldehyde is improved as is the yield of acetone.

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